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(4-Bromophenoxy)trimethylsilane

Basic Information

  • CAS No.:17878-44-3
  • Purity:99%
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Details

Reputable supplier selling (4-Bromophenoxy)trimethylsilane 17878-44-3 with stock

  • Molecular Formula:C9H13BrOSi
  • Molecular Weight:245.191
  • Vapor Pressure:0.216mmHg at 25°C 
  • Refractive Index:n20/D 1.515(lit.)  
  • Boiling Point:215.5 °C at 760 mmHg 
  • Flash Point:97.2 °C 
  • PSA:9.23000 
  • Density:1.236 g/cm3 
  • LogP:3.66280 

(4-Bromophenoxy)trimethylsilane(Cas 17878-44-3) Usage

General Description

"(4-Bromophenoxy)trimethylsilane" is a chemical compound with the molecular formula C9H13BrOSi. The presence of the bromine atom in the structure makes it suitable for use in cross-coupling reactions, a common process in the field of organic synthesis. Furthermore, the silane moiety enhances its volatility, making it an ideal candidate for vapor deposition processes utilized in coating and semiconductor industries. (4-Bromophenoxy)trimethylsilane also demonstrates compatibility with various solvents and reagents, allowing for diversity in chemical reactions. Its handling and storage require caution due to its potential volatility and reactivity.

InChI:InChI=1/C9H13BrOSi/c1-12(2,3)11-9-6-4-8(10)5-7-9/h4-7H,1-3H3

17878-44-3 Relevant articles

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King,F.D.,Walton,D.R.M.

, p. 40 - 42 (1976)

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KF/clinoptilolite NPs: An efficient and heterogeneous catalyst for chemoselective silylation of alcohols and phenols

Oladee, Razieh,Zareyee, Daryoush,Khalilzadeh, Mohammad A.

, p. 731 - 737 (2021/03/31)

Potassium fluoride incorporated on clino...

Use of Silylated Formiates as Hydrosilane Equivalents

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Paragraph 0514, (2021/09/26)

The present invention relates to a metho...

Silylation of Alcohols, Phenols, and Silanols with Alkynylsilanes – an Efficient Route to Silyl Ethers and Unsymmetrical Siloxanes

Kuciński, Krzysztof,Stachowiak, Hanna,Hreczycho, Grzegorz

, p. 4042 - 4049 (2020/07/04)

The formation of several silyl ethers (a...

Preparation method of hydroxyphenylboronic acid

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Paragraph 0034-0036; 0038-0040, (2020/05/08)

The invention discloses a preparation me...

17878-44-3 Process route

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

4-bromo-phenol
106-41-2

4-bromo-phenol

(4-bromophenoxy)trimethylsilane
17878-44-3

(4-bromophenoxy)trimethylsilane

Conditions
Conditions Yield
With triethylamine; In toluene; at 20 ℃; for 21h; Inert atmosphere;
99%
With triethylamine; In tetrahydrofuran;
99%
With triethylamine; In dichloromethane; at 0 - 30 ℃; for 4h;
94.6%
With triethylamine; In Petroleum ether;
80%
With pyridine;
In tetrahydrofuran; triethylamine; for 1h; Ambient temperature;
With urea; In benzene; at 40 - 50 ℃; for 1.5h;
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

trimethylsilyl iodide
16029-98-4

trimethylsilyl iodide

(4-bromophenoxy)trimethylsilane
17878-44-3

(4-bromophenoxy)trimethylsilane

Conditions
Conditions Yield
In chloroform-d1;

17878-44-3 Upstream products

  • 75-77-4
    75-77-4

    chloro-trimethyl-silane

  • 106-41-2
    106-41-2

    4-bromo-phenol

  • 104-92-7
    104-92-7

    1-bromo-4-methoxy-benzene

  • 16029-98-4
    16029-98-4

    trimethylsilyl iodide

17878-44-3 Downstream products

  • 18036-81-2
    18036-81-2

    trimethyl-(4-trimethylsilanyloxy-phenyl)-silane

  • 18588-84-6
    18588-84-6

    dimethyl-bis-(4-trimethylsilanyloxy-phenyl)-silane

  • 57230-15-6
    57230-15-6

    phenoxytrimethylsilan

  • 5189-40-2
    5189-40-2

    2,2-bis(4-hydroxyphenyl)methylenecyclohexane